Technetium (Tc)
Technetium (Tc) is a transition metal with atomic number 43; its most stable known isotope has mass number 97. At room temperature it is a solid that melts at 2,157 °C and boils at 4,262 °C.
Technetium key facts
Technetium at a glance
Identity
| Symbol | Tc |
|---|---|
| Atomic number (Z) | 43 |
| Atomic weight | [97] mass number of the most stable isotope |
| Category | Transition metal |
| Group | 7 |
| Period | 5 |
| Block | d-block |
| CAS number | 7440-26-8 |
Atomic properties
| Electron configuration | [Kr] 4d5 5s2 Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d5 5s2 |
|---|---|
| Electrons per shell | 2, 8, 18, 13, 2 |
| Oxidation states | +4, +7 Less common: -3, -1, +1, +2, +3, +5, +6 |
| Electronegativity (Pauling) | 1.9 |
| First ionisation energy | 7.119 eV (686.9 kJ/mol) 2nd: 15.26 eV · 3rd: 29.55 eV |
| Electron affinity | 0.55 eV |
| Atomic radius (empirical) | 135 pm |
| Covalent radius | 128 pm |
| Van der Waals radius | 216 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 2,157 °C · 3,914.6 °F · 2,430.15 K |
| Boiling point | 4,262 °C · 7,703.6 °F · 4,535.15 K |
| Density | 11 g/cm³ |
| Thermal conductivity | 50.6 W/(m·K) |
| Crystal structure | Hexagonal |
Isotopes & abundance
| Natural occurrence | Trace in nature / mostly synthetic |
|---|---|
| Radioactive | Yes |
| Stable isotopes | 3 |
| Most stable isotope | 97Tc — half-life 4.21 million years |
| Known isotopes | 40 |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Technetium electron configuration
Technetium has 43 electrons. Written in short form, its ground-state configuration is [Kr] 4d5 5s2 — the electrons of the noble gas krypton, plus 4d5 5s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d5 5s2.
Discovery and name
1937 — Carlo Perrier and Emilio Segrè · Italy.
Greek tekhnētos, artificial — the first element made artificially.
Known for
The lightest element with no stable isotopes. Technetium-99m is the most widely used medical radioisotope, in tens of millions of scans a year.
Isotopes of technetium
Technetium has no stable isotopes and does not occur naturally in significant amounts. Its longest-lived known isotope is:
| Isotope | Protons | Neutrons | Half-life |
|---|---|---|---|
| 97Tc | 43 | 54 | 4.21 million years |
40 isotopes of technetium are known in our data set (half-lives as published in nuclear data tables).
Technetium compared with group 7
The other elements in group 7, from top to bottom of the table: