Copper (Cu)
Copper (Cu) is a transition metal with atomic number 29 and a standard atomic weight of 63.546. At room temperature it is a solid that melts at 1,085 °C and boils at 2,560 °C.
Copper key facts
Copper at a glance
Identity
| Symbol | Cu |
|---|---|
| Atomic number (Z) | 29 |
| Atomic weight | 63.546 ± 0.003 (CIAAW 2024) |
| Category | Transition metal |
| Group | 11 |
| Period | 4 |
| Block | d-block |
| CAS number | 7440-50-8 |
Atomic properties
| Electron configuration | [Ar] 3d10 4s1 Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s1 |
|---|---|
| Electrons per shell | 2, 8, 18, 1 |
| Oxidation states | +2 Less common: -2, 0, +1, +3, +4 |
| Electronegativity (Pauling) | 1.9 |
| First ionisation energy | 7.726 eV (745.5 kJ/mol) 2nd: 20.292 eV · 3rd: 36.841 eV |
| Electron affinity | 1.235 eV |
| Atomic radius (empirical) | 135 pm |
| Covalent radius | 112 pm |
| Van der Waals radius | 196 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 1,084.6 °C · 1,984.3 °F · 1,357.77 K |
| Boiling point | 2,560 °C · 4,640 °F · 2,833.15 K |
| Density | 8.96 g/cm³ |
| Specific heat capacity | 0.385 J/(g·K) |
| Thermal conductivity | 401 W/(m·K) |
| Crystal structure | Face-centred cubic |
Isotopes & abundance
| Natural occurrence | Primordial |
|---|---|
| Radioactive | No |
| Natural isotopes (abundance) | 63Cu 69.15%, 65Cu 30.85% |
| Stable isotopes | 6 |
| Known isotopes | 33 |
| Abundance in Earth's crust | 60 mg/kg |
| Abundance in seawater | 0.00025 mg/L |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Copper electron configuration
Copper has 29 electrons. Written in short form, its ground-state configuration is [Ar] 3d10 4s1 — the electrons of the noble gas argon, plus 3d10 4s1.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s1.
An exception to the filling rule. The simple aufbau (Madelung) order predicts 4s2, 3d9, but copper actually has 4s1, 3d10. Half-filled and filled subshells, and the close energies of the outer orbitals, make this arrangement more stable.
Discovery and name
Prehistoric — Known since antiquity.
Latin cuprum, from Cyprus, an ancient source.
Known for
An excellent conductor of electricity used in wiring, motors and electronics. One of the first metals humans worked; bronze and brass are copper alloys.
Isotopes of copper
Naturally occurring copper is a mix of 2 isotopes. Each has 29 protons; they differ in the number of neutrons:
| Isotope | Protons | Neutrons | Natural abundance | Stability |
|---|---|---|---|---|
| 63Cu | 29 | 34 | 69.15% | stable |
| 65Cu | 29 | 36 | 30.85% | stable |
33 isotopes of copper are known in our data set (half-lives as published in nuclear data tables).
Copper compared with group 11
The other elements in group 11, from top to bottom of the table:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Copper | 29 | 63.546 | 1,085 °C | 2,560 °C | 8.96 g/cm³ | 1.9 |
| Silver | 47 | 107.87 | 962 °C | 2,162 °C | 10.5 g/cm³ | 1.93 |
| Gold | 79 | 196.97 | 1,064 °C | 2,836 °C | 19.3 g/cm³ | 2.54 |
| Roentgenium | 111 | [282] | — | — | 28.7 g/cm³ (pred.) | — |