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Transition metalElement 29 · d-block

Copper (Cu)

Copper (Cu) is a transition metal with atomic number 29 and a standard atomic weight of 63.546. At room temperature it is a solid that melts at 1,085 °C and boils at 2,560 °C.

Copper key facts

29CuCopper63.546
Atomic number
29
protons
Atomic weight
63.546
CIAAW 2024
Melting point
1,085 °C
1,357.77 K
Boiling point
2,560 °C
2,833.15 K
Density
8.96 g/cm³
near room temperature
Electronegativity
1.9
Pauling scale
State at 25 °C
Solid
 
Discovered
Prehistoric
 

Copper at a glance

Identity

SymbolCu
Atomic number (Z)29
Atomic weight63.546 ± 0.003 (CIAAW 2024)
CategoryTransition metal
Group11
Period4
Blockd-block
CAS number7440-50-8

Atomic properties

Electron configuration[Ar] 3d10 4s1
Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s1
Electrons per shell2, 8, 18, 1
Oxidation states+2
Less common: -2, 0, +1, +3, +4
Electronegativity (Pauling)1.9
First ionisation energy7.726 eV (745.5 kJ/mol)
2nd: 20.292 eV · 3rd: 36.841 eV
Electron affinity1.235 eV
Atomic radius (empirical)135 pm
Covalent radius112 pm
Van der Waals radius196 pm

Physical properties

State at 25 °CSolid
Melting point1,084.6 °C · 1,984.3 °F · 1,357.77 K
Boiling point2,560 °C · 4,640 °F · 2,833.15 K
Density8.96 g/cm³
Specific heat capacity0.385 J/(g·K)
Thermal conductivity401 W/(m·K)
Crystal structureFace-centred cubic

Isotopes & abundance

Natural occurrencePrimordial
RadioactiveNo
Natural isotopes (abundance)63Cu 69.15%, 65Cu 30.85%
Stable isotopes6
Known isotopes33
Abundance in Earth's crust60 mg/kg
Abundance in seawater0.00025 mg/L

Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.

Copper electron configuration

Copper has 29 electrons. Written in short form, its ground-state configuration is [Ar] 3d10 4s1 — the electrons of the noble gas argon, plus 3d10 4s1.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s1.

An exception to the filling rule. The simple aufbau (Madelung) order predicts 4s2, 3d9, but copper actually has 4s1, 3d10. Half-filled and filled subshells, and the close energies of the outer orbitals, make this arrangement more stable.

Cu
3d↑↓↑↓↑↓↑↓↑↓
4s↑

Discovery and name

Discovered

Prehistoric — Known since antiquity.

Name

Latin cuprum, from Cyprus, an ancient source.

Known for

An excellent conductor of electricity used in wiring, motors and electronics. One of the first metals humans worked; bronze and brass are copper alloys.

Isotopes of copper

Naturally occurring copper is a mix of 2 isotopes. Each has 29 protons; they differ in the number of neutrons:

IsotopeProtonsNeutronsNatural abundanceStability
63Cu293469.15%stable
65Cu293630.85%stable

33 isotopes of copper are known in our data set (half-lives as published in nuclear data tables).

Copper compared with group 11

The other elements in group 11, from top to bottom of the table:

ElementZAtomic weightMelting pointBoiling pointDensityElectronegativity
Copper2963.5461,085 °C2,560 °C8.96 g/cm³1.9
Silver47107.87962 °C2,162 °C10.5 g/cm³1.93
Gold79196.971,064 °C2,836 °C19.3 g/cm³2.54
Roentgenium111[282]——28.7 g/cm³ (pred.)—

Frequently asked questions

6 answers
What is the atomic mass of copper?
The standard atomic weight of copper is 63.546 ± 0.003 (CIAAW 2024), so one mole weighs about 63.546 grams.
How many protons, neutrons and electrons does copper have?
A neutral copper atom has 29 protons and 29 electrons. Its most common isotope, copper-63, has 34 neutrons.
What is the electron configuration of copper?
[Ar] 3d¹⁰ 4s¹ (in full: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s¹).
What are the melting and boiling points of copper?
Copper melts at 1,084.62 °C (1,984.3 °F) and boils at 2,560 °C (4,640 °F).
Is copper a metal?
Copper is a metal. It is in group 11, period 4, and is a solid at room temperature.
Who discovered copper?
Copper has been known since ancient times.