Plutonium (Pu)
Plutonium (Pu) is an actinide with atomic number 94; its most stable known isotope has mass number 244. At room temperature it is a solid that melts at 640 °C and boils at 3,228 °C.
Plutonium key facts
Plutonium at a glance
Identity
| Symbol | Pu |
|---|---|
| Atomic number (Z) | 94 |
| Atomic weight | [244] mass number of the most stable isotope |
| Category | Actinide |
| Group | — (f-block: actinide series) |
| Period | 7 |
| Block | f-block |
| CAS number | 7440-07-5 |
Atomic properties
| Electron configuration | [Rn] 5f6 7s2 Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f6 6s2 6p6 7s2 |
|---|---|
| Electrons per shell | 2, 8, 18, 32, 24, 8, 2 |
| Oxidation states | +4 Less common: +2, +3, +5, +6, +7, +8 |
| Electronegativity (Pauling) | 1.28 |
| First ionisation energy | 6.026 eV (581.4 kJ/mol) 2nd: 11.5 eV · 3rd: 21.1 eV |
| Atomic radius (empirical) | 175 pm |
| Covalent radius | 172 pm |
| Van der Waals radius | 243 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 640 °C · 1,184 °F · 913.15 K |
| Boiling point | 3,228 °C · 5,842.4 °F · 3,501.15 K |
| Density | 19.7 g/cm³ |
| Crystal structure | Monoclinic |
Isotopes & abundance
| Natural occurrence | Synthetic (traces in uranium ores) |
|---|---|
| Radioactive | Yes |
| Most stable isotope | 244Pu — half-life 81.3 million years |
| Known isotopes | 27 |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Plutonium electron configuration
Plutonium has 94 electrons. Written in short form, its ground-state configuration is [Rn] 5f6 7s2 — the electrons of the noble gas radon, plus 5f6 7s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f6 6s2 6p6 7s2.
Discovery and name
1940–1941 — Glenn T. Seaborg, Arthur Wahl, Joseph W. Kennedy and Edwin McMillan · United States (Berkeley).
The dwarf planet Pluto.
Known for
Plutonium-239 is used in nuclear weapons and MOX reactor fuel; plutonium-238 powers spacecraft such as Voyager and the Mars rovers.
Isotopes of plutonium
Plutonium has no stable isotopes and does not occur naturally in significant amounts. Its longest-lived known isotope is:
| Isotope | Protons | Neutrons | Half-life |
|---|---|---|---|
| 244Pu | 94 | 150 | 81.3 million years |
27 isotopes of plutonium are known in our data set (half-lives as published in nuclear data tables).
Plutonium and its neighbours in the actinide series
Neighbouring elements in the same f-block series:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Protactinium | 91 | 231.04 | 1,572 °C | — | 15.4 g/cm³ | 1.5 |
| Uranium | 92 | 238.03 | 1,135 °C | 4,131 °C | 19.1 g/cm³ | 1.38 |
| Neptunium | 93 | [237] | 644 °C | — | 20.2 g/cm³ | 1.36 |
| Plutonium | 94 | [244] | 640 °C | 3,228 °C | 19.7 g/cm³ | 1.28 |
| Americium | 95 | [243] | 1,176 °C | — | 12 g/cm³ | 1.3 |
| Curium | 96 | [247] | 1,345 °C | — | 13.51 g/cm³ | 1.3 |
| Berkelium | 97 | [247] | 986 °C | — | 14.78 g/cm³ | 1.3 |