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ActinideElement 94 · f-block

Plutonium (Pu)

Plutonium (Pu) is an actinide with atomic number 94; its most stable known isotope has mass number 244. At room temperature it is a solid that melts at 640 °C and boils at 3,228 °C.

Plutonium key facts

94PuPlutonium[244]
Atomic number
94
protons
Atomic weight
[244]
most stable isotope
Melting point
640 °C
913.15 K
Boiling point
3,228 °C
3,501.15 K
Density
19.7 g/cm³
near room temperature
Electronegativity
1.28
Pauling scale
State at 25 °C
Solid
 
Discovered
1940–1941
United States (Berkeley)

Plutonium at a glance

Identity

SymbolPu
Atomic number (Z)94
Atomic weight[244] mass number of the most stable isotope
CategoryActinide
Group— (f-block: actinide series)
Period7
Blockf-block
CAS number7440-07-5

Atomic properties

Electron configuration[Rn] 5f6 7s2
Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f6 6s2 6p6 7s2
Electrons per shell2, 8, 18, 32, 24, 8, 2
Oxidation states+4
Less common: +2, +3, +5, +6, +7, +8
Electronegativity (Pauling)1.28
First ionisation energy6.026 eV (581.4 kJ/mol)
2nd: 11.5 eV · 3rd: 21.1 eV
Atomic radius (empirical)175 pm
Covalent radius172 pm
Van der Waals radius243 pm

Physical properties

State at 25 °CSolid
Melting point640 °C · 1,184 °F · 913.15 K
Boiling point3,228 °C · 5,842.4 °F · 3,501.15 K
Density19.7 g/cm³
Crystal structureMonoclinic

Isotopes & abundance

Natural occurrenceSynthetic (traces in uranium ores)
RadioactiveYes
Most stable isotope244Pu — half-life 81.3 million years
Known isotopes27

Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.

Plutonium electron configuration

Plutonium has 94 electrons. Written in short form, its ground-state configuration is [Rn] 5f6 7s2 — the electrons of the noble gas radon, plus 5f6 7s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f6 6s2 6p6 7s2.

Pu
5f↑↑↑↑↑↑ 
7s↑↓

Discovery and name

Discovered

1940–1941 — Glenn T. Seaborg, Arthur Wahl, Joseph W. Kennedy and Edwin McMillan · United States (Berkeley).

Name

The dwarf planet Pluto.

Known for

Plutonium-239 is used in nuclear weapons and MOX reactor fuel; plutonium-238 powers spacecraft such as Voyager and the Mars rovers.

Isotopes of plutonium

Plutonium has no stable isotopes and does not occur naturally in significant amounts. Its longest-lived known isotope is:

IsotopeProtonsNeutronsHalf-life
244Pu9415081.3 million years

27 isotopes of plutonium are known in our data set (half-lives as published in nuclear data tables).

Plutonium and its neighbours in the actinide series

Neighbouring elements in the same f-block series:

ElementZAtomic weightMelting pointBoiling pointDensityElectronegativity
Protactinium91231.041,572 °C—15.4 g/cm³1.5
Uranium92238.031,135 °C4,131 °C19.1 g/cm³1.38
Neptunium93[237]644 °C—20.2 g/cm³1.36
Plutonium94[244]640 °C3,228 °C19.7 g/cm³1.28
Americium95[243]1,176 °C—12 g/cm³1.3
Curium96[247]1,345 °C—13.51 g/cm³1.3
Berkelium97[247]986 °C—14.78 g/cm³1.3

Frequently asked questions

6 answers
What is the atomic mass of plutonium?
Plutonium has no stable isotopes, so it has no standard atomic weight. Periodic tables show [244], the mass number of its most stable known isotope.
How many protons, neutrons and electrons does plutonium have?
A neutral plutonium atom has 94 protons and 94 electrons. Its most stable isotope, plutonium-244, has 150 neutrons.
What is the electron configuration of plutonium?
[Rn] 5f⁶ 7s² (in full: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 5f⁶ 6s² 6p⁶ 7s²).
What are the melting and boiling points of plutonium?
Plutonium melts at 640 °C (1,184 °F) and boils at 3,228 °C (5,842.4 °F).
Is plutonium a metal?
Plutonium is a metal. It is in the f-block, period 7, and is a solid at room temperature.
Who discovered plutonium?
1940–1941 — Glenn T. Seaborg, Arthur Wahl, Joseph W. Kennedy and Edwin McMillan (United States (Berkeley)).