Boron (B)
Boron (B) is a metalloid with atomic number 5 and a standard atomic weight of 10.81. At room temperature it is a solid that melts at 2,077 °C and boils at 4,000 °C.
Boron key facts
Boron at a glance
Identity
| Symbol | B |
|---|---|
| Atomic number (Z) | 5 |
| Atomic weight | 10.81 ± 0.02 (CIAAW 2024) |
| Category | Metalloid |
| Group | 13 — boron group |
| Period | 2 |
| Block | p-block |
| CAS number | 7440-42-8 |
Atomic properties
| Electron configuration | [He] 2s2 2p1 Full: 1s2 2s2 2p1 |
|---|---|
| Electrons per shell | 2, 3 |
| Oxidation states | +3 Less common: -5, -1, 0, +1, +2 |
| Electronegativity (Pauling) | 2.04 |
| First ionisation energy | 8.298 eV (800.6 kJ/mol) 2nd: 25.155 eV · 3rd: 37.931 eV |
| Electron affinity | 0.28 eV |
| Atomic radius (empirical) | 85 pm |
| Covalent radius | 85 pm |
| Van der Waals radius | 192 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 2,077 °C · 3,770.6 °F · 2,350.15 K |
| Boiling point | 4,000 °C · 7,232 °F · 4,273.15 K |
| Density | 2.34 g/cm³ |
| Specific heat capacity | 1.026 J/(g·K) |
| Thermal conductivity | 27.4 W/(m·K) |
| Crystal structure | Tetragonal |
Isotopes & abundance
| Natural occurrence | Primordial |
|---|---|
| Radioactive | No |
| Natural isotopes (abundance) | 11B 80.35%, 10B 19.65% |
| Stable isotopes | 3 |
| Known isotopes | 16 |
| Abundance in Earth's crust | 10 mg/kg |
| Abundance in seawater | 4.44 mg/L |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Boron electron configuration
Boron has 5 electrons. Written in short form, its ground-state configuration is [He] 2s2 2p1 — the electrons of the noble gas helium, plus 2s2 2p1.Written out in full: 1s2 2s2 2p1.
As a member of group 13 it has 3 valence electrons in its outer shell (shell 2), which largely decide its chemistry.
Discovery and name
1808 — Joseph Louis Gay-Lussac and Louis Jacques Thénard; Humphry Davy · France / England.
From borax, the mineral it was isolated from.
Known for
Borosilicate glass (Pyrex), boron fibres, detergents and neodymium magnets (Nd₂Fe₁₄B) all rely on boron; boron-10 absorbs neutrons in nuclear control rods.
Isotopes of boron
Naturally occurring boron is a mix of 2 isotopes. Each has 5 protons; they differ in the number of neutrons:
| Isotope | Protons | Neutrons | Natural abundance | Stability |
|---|---|---|---|---|
| 11B | 5 | 6 | 80.35% | stable |
| 10B | 5 | 5 | 19.65% | stable |
16 isotopes of boron are known in our data set (half-lives as published in nuclear data tables).
Boron compared with group 13
The other elements in group 13 (boron group), from top to bottom of the table:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Boron | 5 | 10.81 | 2,077 °C | 4,000 °C | 2.34 g/cm³ | 2.04 |
| Aluminum | 13 | 26.982 | 660 °C | 2,519 °C | 2.7 g/cm³ | 1.61 |
| Gallium | 31 | 69.723 | 30 °C | 2,229 °C | 5.91 g/cm³ | 1.81 |
| Indium | 49 | 114.82 | 157 °C | 2,027 °C | 7.31 g/cm³ | 1.78 |
| Thallium | 81 | 204.38 | 304 °C | 1,473 °C | 11.8 g/cm³ | 1.62 |
| Nihonium | 113 | [286] | — | — | 16 g/cm³ (pred.) | — |