Iron (Fe)
Iron (Fe) is a transition metal with atomic number 26 and a standard atomic weight of 55.845. At room temperature it is a solid that melts at 1,538 °C and boils at 2,861 °C.
Iron key facts
Iron at a glance
Identity
| Symbol | Fe |
|---|---|
| Atomic number (Z) | 26 |
| Atomic weight | 55.845 ± 0.002 (CIAAW 2024) |
| Category | Transition metal |
| Group | 8 |
| Period | 4 |
| Block | d-block |
| CAS number | 7439-89-6 |
Atomic properties
| Electron configuration | [Ar] 3d6 4s2 Full: 1s2 2s2 2p6 3s2 3p6 3d6 4s2 |
|---|---|
| Electrons per shell | 2, 8, 14, 2 |
| Oxidation states | +2, +3 Less common: -4, -2, -1, 0, +1, +4, +5, +6, +7 |
| Electronegativity (Pauling) | 1.83 |
| First ionisation energy | 7.902 eV (762.5 kJ/mol) 2nd: 16.199 eV · 3rd: 30.651 eV |
| Electron affinity | 0.151 eV |
| Atomic radius (empirical) | 140 pm |
| Covalent radius | 116 pm |
| Van der Waals radius | 204 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 1,538 °C · 2,800.4 °F · 1,811.15 K |
| Boiling point | 2,861 °C · 5,181.8 °F · 3,134.15 K |
| Density | 7.87 g/cm³ |
| Specific heat capacity | 0.449 J/(g·K) |
| Thermal conductivity | 80.4 W/(m·K) |
| Crystal structure | Body-centred cubic |
Isotopes & abundance
| Natural occurrence | Primordial |
|---|---|
| Radioactive | No |
| Natural isotopes (abundance) | 56Fe 91.754%, 54Fe 5.845%, 57Fe 2.119%, 58Fe 0.282% |
| Stable isotopes | 4 |
| Known isotopes | 32 |
| Abundance in Earth's crust | 56,300 mg/kg |
| Abundance in seawater | 0.002 mg/L |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Iron electron configuration
Iron has 26 electrons. Written in short form, its ground-state configuration is [Ar] 3d6 4s2 — the electrons of the noble gas argon, plus 3d6 4s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d6 4s2.
Discovery and name
Prehistoric — Known since antiquity.
Anglo-Saxon iren; the symbol Fe is from Latin ferrum.
Known for
The most-used metal: steel is iron with a little carbon. Earth's core is mostly iron, and haemoglobin uses iron to carry oxygen in the blood.
Isotopes of iron
Naturally occurring iron is a mix of 4 isotopes. Each has 26 protons; they differ in the number of neutrons:
| Isotope | Protons | Neutrons | Natural abundance | Stability |
|---|---|---|---|---|
| 56Fe | 26 | 30 | 91.754% | stable |
| 54Fe | 26 | 28 | 5.845% | stable |
| 57Fe | 26 | 31 | 2.119% | stable |
| 58Fe | 26 | 32 | 0.282% | stable |
32 isotopes of iron are known in our data set (half-lives as published in nuclear data tables).
Iron compared with group 8
The other elements in group 8, from top to bottom of the table: