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Transition metalElement 26 · d-block

Iron (Fe)

Iron (Fe) is a transition metal with atomic number 26 and a standard atomic weight of 55.845. At room temperature it is a solid that melts at 1,538 °C and boils at 2,861 °C.

Iron key facts

26FeIron55.845
Atomic number
26
protons
Atomic weight
55.845
CIAAW 2024
Melting point
1,538 °C
1,811.15 K
Boiling point
2,861 °C
3,134.15 K
Density
7.87 g/cm³
near room temperature
Electronegativity
1.83
Pauling scale
State at 25 °C
Solid
 
Discovered
Prehistoric
 

Iron at a glance

Identity

SymbolFe
Atomic number (Z)26
Atomic weight55.845 ± 0.002 (CIAAW 2024)
CategoryTransition metal
Group8
Period4
Blockd-block
CAS number7439-89-6

Atomic properties

Electron configuration[Ar] 3d6 4s2
Full: 1s2 2s2 2p6 3s2 3p6 3d6 4s2
Electrons per shell2, 8, 14, 2
Oxidation states+2, +3
Less common: -4, -2, -1, 0, +1, +4, +5, +6, +7
Electronegativity (Pauling)1.83
First ionisation energy7.902 eV (762.5 kJ/mol)
2nd: 16.199 eV · 3rd: 30.651 eV
Electron affinity0.151 eV
Atomic radius (empirical)140 pm
Covalent radius116 pm
Van der Waals radius204 pm

Physical properties

State at 25 °CSolid
Melting point1,538 °C · 2,800.4 °F · 1,811.15 K
Boiling point2,861 °C · 5,181.8 °F · 3,134.15 K
Density7.87 g/cm³
Specific heat capacity0.449 J/(g·K)
Thermal conductivity80.4 W/(m·K)
Crystal structureBody-centred cubic

Isotopes & abundance

Natural occurrencePrimordial
RadioactiveNo
Natural isotopes (abundance)56Fe 91.754%, 54Fe 5.845%, 57Fe 2.119%, 58Fe 0.282%
Stable isotopes4
Known isotopes32
Abundance in Earth's crust56,300 mg/kg
Abundance in seawater0.002 mg/L

Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.

Iron electron configuration

Iron has 26 electrons. Written in short form, its ground-state configuration is [Ar] 3d6 4s2 — the electrons of the noble gas argon, plus 3d6 4s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d6 4s2.

Fe
3d↑↓↑↑↑↑
4s↑↓

Discovery and name

Discovered

Prehistoric — Known since antiquity.

Name

Anglo-Saxon iren; the symbol Fe is from Latin ferrum.

Known for

The most-used metal: steel is iron with a little carbon. Earth's core is mostly iron, and haemoglobin uses iron to carry oxygen in the blood.

Isotopes of iron

Naturally occurring iron is a mix of 4 isotopes. Each has 26 protons; they differ in the number of neutrons:

IsotopeProtonsNeutronsNatural abundanceStability
56Fe263091.754%stable
54Fe26285.845%stable
57Fe26312.119%stable
58Fe26320.282%stable

32 isotopes of iron are known in our data set (half-lives as published in nuclear data tables).

Iron compared with group 8

The other elements in group 8, from top to bottom of the table:

ElementZAtomic weightMelting pointBoiling pointDensityElectronegativity
Iron2655.8451,538 °C2,861 °C7.87 g/cm³1.83
Ruthenium44101.072,333 °C4,147 °C12.1 g/cm³2.2
Osmium76190.233,033 °C5,008 °C22.587 g/cm³2.2
Hassium108[269]——40.7 g/cm³ (pred.)—

Frequently asked questions

6 answers
What is the atomic mass of iron?
The standard atomic weight of iron is 55.845 ± 0.002 (CIAAW 2024), so one mole weighs about 55.845 grams.
How many protons, neutrons and electrons does iron have?
A neutral iron atom has 26 protons and 26 electrons. Its most common isotope, iron-56, has 30 neutrons.
What is the electron configuration of iron?
[Ar] 3d⁶ 4s² (in full: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁶ 4s²).
What are the melting and boiling points of iron?
Iron melts at 1,538 °C (2,800.4 °F) and boils at 2,861 °C (5,181.8 °F).
Is iron a metal?
Iron is a metal. It is in group 8, period 4, and is a solid at room temperature.
Who discovered iron?
Iron has been known since ancient times.