Germanium (Ge)
Germanium (Ge) is a metalloid with atomic number 32 and a standard atomic weight of 72.630. At room temperature it is a solid that melts at 938 °C and boils at 2,833 °C.
Germanium key facts
Germanium at a glance
Identity
| Symbol | Ge |
|---|---|
| Atomic number (Z) | 32 |
| Atomic weight | 72.630 ± 0.008 (CIAAW 2024) |
| Category | Metalloid |
| Group | 14 — carbon group |
| Period | 4 |
| Block | p-block |
| CAS number | 7440-56-4 |
Atomic properties
| Electron configuration | [Ar] 3d10 4s2 4p2 Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2 |
|---|---|
| Electrons per shell | 2, 8, 18, 4 |
| Oxidation states | -4, +2, +4 Less common: -3, -2, -1, 0, +1, +3 |
| Electronegativity (Pauling) | 2.01 |
| First ionisation energy | 7.899 eV (762.2 kJ/mol) 2nd: 15.935 eV · 3rd: 34.058 eV |
| Electron affinity | 1.233 eV |
| Atomic radius (empirical) | 125 pm |
| Covalent radius | 121 pm |
| Van der Waals radius | 211 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 938.3 °C · 1,720.9 °F · 1,211.4 K |
| Boiling point | 2,833 °C · 5,131.4 °F · 3,106.15 K |
| Density | 5.3234 g/cm³ |
| Specific heat capacity | 0.32 J/(g·K) |
| Thermal conductivity | 60.2 W/(m·K) |
| Crystal structure | Diamond cubic |
Isotopes & abundance
| Natural occurrence | Primordial |
|---|---|
| Radioactive | No |
| Natural isotopes (abundance) | 74Ge 36.52%, 72Ge 27.45%, 70Ge 20.52%, 73Ge 7.76%, 76Ge 7.75% (radioactive) |
| Stable isotopes | 5 |
| Known isotopes | 33 |
| Abundance in Earth's crust | 1.5 mg/kg |
| Abundance in seawater | 0.00005 mg/L |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Germanium electron configuration
Germanium has 32 electrons. Written in short form, its ground-state configuration is [Ar] 3d10 4s2 4p2 — the electrons of the noble gas argon, plus 3d10 4s2 4p2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2.
As a member of group 14 it has 4 valence electrons in its outer shell (shell 4), which largely decide its chemistry.
Discovery and name
1886 — Clemens Winkler · Germany.
Latin Germania, Germany.
Known for
A semiconductor predicted by Mendeleev as 'eka-silicon'. Used in fibre optics, infrared optics and early transistors.
Isotopes of germanium
Naturally occurring germanium is a mix of 5 isotopes. Each has 32 protons; they differ in the number of neutrons:
| Isotope | Protons | Neutrons | Natural abundance | Stability |
|---|---|---|---|---|
| 74Ge | 32 | 42 | 36.52% | stable |
| 72Ge | 32 | 40 | 27.45% | stable |
| 70Ge | 32 | 38 | 20.52% | stable |
| 73Ge | 32 | 41 | 7.76% | stable |
| 76Ge | 32 | 44 | 7.75% | radioactive · half-life 1.88 × 10²¹ years |
33 isotopes of germanium are known in our data set (half-lives as published in nuclear data tables).
Germanium compared with group 14
The other elements in group 14 (carbon group), from top to bottom of the table:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Carbon | 6 | 12.011 | — | 3,642 °C | 2.2 g/cm³ | 2.55 |
| Silicon | 14 | 28.085 | 1,414 °C | 3,265 °C | 2.33 g/cm³ | 1.9 |
| Germanium | 32 | 72.630 | 938 °C | 2,833 °C | 5.323 g/cm³ | 2.01 |
| Tin | 50 | 118.71 | 232 °C | 2,586 °C | 7.287 g/cm³ | 1.96 |
| Lead | 82 | 207.2 | 327 °C | 1,749 °C | 11.3 g/cm³ | 2.33 |
| Flerovium | 114 | [290] | — | — | 9.928 g/cm³ (pred.) | — |