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MetalloidElement 32 · p-block

Germanium (Ge)

Germanium (Ge) is a metalloid with atomic number 32 and a standard atomic weight of 72.630. At room temperature it is a solid that melts at 938 °C and boils at 2,833 °C.

Germanium key facts

32GeGermanium72.630
Atomic number
32
protons
Atomic weight
72.630
CIAAW 2024
Melting point
938 °C
1,211.4 K
Boiling point
2,833 °C
3,106.15 K
Density
5.323 g/cm³
near room temperature
Electronegativity
2.01
Pauling scale
State at 25 °C
Solid
 
Discovered
1886
Germany

Germanium at a glance

Identity

SymbolGe
Atomic number (Z)32
Atomic weight72.630 ± 0.008 (CIAAW 2024)
CategoryMetalloid
Group14 — carbon group
Period4
Blockp-block
CAS number7440-56-4

Atomic properties

Electron configuration[Ar] 3d10 4s2 4p2
Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2
Electrons per shell2, 8, 18, 4
Oxidation states-4, +2, +4
Less common: -3, -2, -1, 0, +1, +3
Electronegativity (Pauling)2.01
First ionisation energy7.899 eV (762.2 kJ/mol)
2nd: 15.935 eV · 3rd: 34.058 eV
Electron affinity1.233 eV
Atomic radius (empirical)125 pm
Covalent radius121 pm
Van der Waals radius211 pm

Physical properties

State at 25 °CSolid
Melting point938.3 °C · 1,720.9 °F · 1,211.4 K
Boiling point2,833 °C · 5,131.4 °F · 3,106.15 K
Density5.3234 g/cm³
Specific heat capacity0.32 J/(g·K)
Thermal conductivity60.2 W/(m·K)
Crystal structureDiamond cubic

Isotopes & abundance

Natural occurrencePrimordial
RadioactiveNo
Natural isotopes (abundance)74Ge 36.52%, 72Ge 27.45%, 70Ge 20.52%, 73Ge 7.76%, 76Ge 7.75% (radioactive)
Stable isotopes5
Known isotopes33
Abundance in Earth's crust1.5 mg/kg
Abundance in seawater0.00005 mg/L

Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.

Germanium electron configuration

Germanium has 32 electrons. Written in short form, its ground-state configuration is [Ar] 3d10 4s2 4p2 — the electrons of the noble gas argon, plus 3d10 4s2 4p2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2.

As a member of group 14 it has 4 valence electrons in its outer shell (shell 4), which largely decide its chemistry.

Ge
3d↑↓↑↓↑↓↑↓↑↓
4s↑↓
4p↑↑ 

Discovery and name

Discovered

1886 — Clemens Winkler · Germany.

Name

Latin Germania, Germany.

Known for

A semiconductor predicted by Mendeleev as 'eka-silicon'. Used in fibre optics, infrared optics and early transistors.

Isotopes of germanium

Naturally occurring germanium is a mix of 5 isotopes. Each has 32 protons; they differ in the number of neutrons:

IsotopeProtonsNeutronsNatural abundanceStability
74Ge324236.52%stable
72Ge324027.45%stable
70Ge323820.52%stable
73Ge32417.76%stable
76Ge32447.75%radioactive · half-life 1.88 × 10²¹ years

33 isotopes of germanium are known in our data set (half-lives as published in nuclear data tables).

Germanium compared with group 14

The other elements in group 14 (carbon group), from top to bottom of the table:

ElementZAtomic weightMelting pointBoiling pointDensityElectronegativity
Carbon612.011—3,642 °C2.2 g/cm³2.55
Silicon1428.0851,414 °C3,265 °C2.33 g/cm³1.9
Germanium3272.630938 °C2,833 °C5.323 g/cm³2.01
Tin50118.71232 °C2,586 °C7.287 g/cm³1.96
Lead82207.2327 °C1,749 °C11.3 g/cm³2.33
Flerovium114[290]——9.928 g/cm³ (pred.)—

Frequently asked questions

6 answers
What is the atomic mass of germanium?
The standard atomic weight of germanium is 72.630 ± 0.008 (CIAAW 2024), so one mole weighs about 72.630 grams.
How many protons, neutrons and electrons does germanium have?
A neutral germanium atom has 32 protons and 32 electrons. Its most common isotope, germanium-74, has 42 neutrons.
What is the electron configuration of germanium?
[Ar] 3d¹⁰ 4s² 4p² (in full: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p²).
What are the melting and boiling points of germanium?
Germanium melts at 938.25 °C (1,720.9 °F) and boils at 2,833 °C (5,131.4 °F).
Is germanium a metal?
Germanium is a metalloid — it has properties between metals and nonmetals. It is in group 14, period 4, and is a solid at room temperature.
Who discovered germanium?
1886 — Clemens Winkler (Germany).