Nitrogen (N)
Nitrogen (N) is a reactive nonmetal with atomic number 7 and a standard atomic weight of 14.007. At room temperature it is a gas that melts at -210 °C and boils at -196 °C.
Nitrogen key facts
Nitrogen at a glance
Identity
| Symbol | N |
|---|---|
| Atomic number (Z) | 7 |
| Atomic weight | 14.007 ± 0.001 (CIAAW 2024) |
| Category | Reactive nonmetal |
| Group | 15 — pnictogens (nitrogen group) |
| Period | 2 |
| Block | p-block |
| CAS number | 7727-37-9 |
Atomic properties
| Electron configuration | [He] 2s2 2p3 Full: 1s2 2s2 2p3 |
|---|---|
| Electrons per shell | 2, 5 |
| Oxidation states | -3, +3, +5 Less common: -2, -1, 0, +1, +2, +4 |
| Electronegativity (Pauling) | 3.04 |
| First ionisation energy | 14.534 eV (1,402.3 kJ/mol) 2nd: 29.601 eV · 3rd: 47.445 eV |
| Atomic radius (empirical) | 65 pm |
| Covalent radius | 71 pm |
| Van der Waals radius | 155 pm |
Physical properties
| State at 25 °C | Gas |
|---|---|
| Melting point | -210 °C · -346 °F · 63.15 K |
| Boiling point | -195.8 °C · -320.4 °F · 77.35 K |
| Density | 1.2506 g/L (gas at 0 °C, 1 atm) |
| Specific heat capacity | 1.04 J/(g·K) |
| Thermal conductivity | 0.026 W/(m·K) |
| Crystal structure | Hexagonal |
Isotopes & abundance
| Natural occurrence | Primordial |
|---|---|
| Radioactive | No |
| Natural isotopes (abundance) | 14N 99.6205%, 15N 0.3795% |
| Stable isotopes | 4 |
| Known isotopes | 16 |
| Abundance in Earth's crust | 19 mg/kg |
| Abundance in seawater | 0.5 mg/L |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Nitrogen electron configuration
Nitrogen has 7 electrons. Written in short form, its ground-state configuration is [He] 2s2 2p3 — the electrons of the noble gas helium, plus 2s2 2p3.Written out in full: 1s2 2s2 2p3.
As a member of group 15 it has 5 valence electrons in its outer shell (shell 2), which largely decide its chemistry.
Discovery and name
1772 — Daniel Rutherford · Scotland.
Greek nitron + genes — 'nitre-forming' (saltpetre).
Known for
Makes up about 78% of Earth's air. Fixed into ammonia by the Haber–Bosch process, it feeds roughly half the world's population via fertilisers; liquid nitrogen boils at −196 °C.
Isotopes of nitrogen
Naturally occurring nitrogen is a mix of 2 isotopes. Each has 7 protons; they differ in the number of neutrons:
| Isotope | Protons | Neutrons | Natural abundance | Stability |
|---|---|---|---|---|
| 14N | 7 | 7 | 99.6205% | stable |
| 15N | 7 | 8 | 0.3795% | stable |
16 isotopes of nitrogen are known in our data set (half-lives as published in nuclear data tables).
Nitrogen compared with group 15
The other elements in group 15 (pnictogens (nitrogen group)), from top to bottom of the table:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Nitrogen | 7 | 14.007 | -210 °C | -196 °C | 1.2506 g/L | 3.04 |
| Phosphorus | 15 | 30.974 | 44 °C | 281 °C | 1.823 g/cm³ | 2.19 |
| Arsenic | 33 | 74.922 | — | 614 °C | 5.75 g/cm³ | 2.18 |
| Antimony | 51 | 121.76 | 631 °C | 1,587 °C | 6.68 g/cm³ | 2.05 |
| Bismuth | 83 | 208.98 | 271 °C | 1,564 °C | 9.79 g/cm³ | 2.02 |
| Moscovium | 115 | [290] | — | — | 13.5 g/cm³ (pred.) | — |