Actinium (Ac)
Actinium (Ac) is an actinide with atomic number 89; its most stable known isotope has mass number 227. At room temperature it is a solid that melts at 1,050 °C and boils at 3,200 °C.
Actinium key facts
Actinium at a glance
Identity
| Symbol | Ac |
|---|---|
| Atomic number (Z) | 89 |
| Atomic weight | [227] mass number of the most stable isotope |
| Category | Actinide |
| Group | — (f-block: lanthanide series) |
| Period | 7 |
| Block | d-block |
| CAS number | 7440-34-8 |
Atomic properties
| Electron configuration | [Rn] 6d1 7s2 Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p6 6d1 7s2 |
|---|---|
| Electrons per shell | 2, 8, 18, 32, 18, 9, 2 |
| Oxidation states | +3 |
| Electronegativity (Pauling) | 1.1 |
| First ionisation energy | 5.38 eV (519.1 kJ/mol) 2nd: 11.75 eV · 3rd: 17.436 eV |
| Electron affinity | 0.35 eV |
| Atomic radius (empirical) | 195 pm |
| Covalent radius | 186 pm |
| Van der Waals radius | 247 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 1,050 °C · 1,922 °F · 1,323.15 K |
| Boiling point | 3,200 °C · 5,792 °F · 3,473.15 K |
| Density | 10 g/cm³ |
| Specific heat capacity | 0.12 J/(g·K) |
| Crystal structure | Face-centred cubic |
Isotopes & abundance
| Natural occurrence | From radioactive decay |
|---|---|
| Radioactive | Yes |
| Most stable isotope | 227Ac — half-life 21.772 years |
| Known isotopes | 33 |
| Abundance in Earth's crust | 0 mg/kg |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Actinium electron configuration
Actinium has 89 electrons. Written in short form, its ground-state configuration is [Rn] 6d1 7s2 — the electrons of the noble gas radon, plus 6d1 7s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p6 6d1 7s2.
An exception to the filling rule. The simple aufbau (Madelung) order predicts 5f1, 6d0, but actinium actually has 5f0, 6d1. Half-filled and filled subshells, and the close energies of the outer orbitals, make this arrangement more stable.
Discovery and name
1899 — André-Louis Debierne; independently Friedrich Oskar Giesel (1902) · France / Germany.
Greek aktis, ray.
Known for
Glows blue in the dark from its radioactivity. Actinium-225 is used in targeted alpha therapy for cancer.
Isotopes of actinium
Actinium has no stable isotopes. Its longest-lived known isotope is:
| Isotope | Protons | Neutrons | Half-life |
|---|---|---|---|
| 227Ac | 89 | 138 | 21.772 years |
33 isotopes of actinium are known in our data set (half-lives as published in nuclear data tables).
Actinium and its neighbours in the actinide series
Neighbouring elements in the same f-block series:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Actinium | 89 | [227] | 1,050 °C | 3,200 °C | 10 g/cm³ | 1.1 |
| Thorium | 90 | 232.04 | 1,750 °C | 4,785 °C | 11.7 g/cm³ | 1.3 |
| Protactinium | 91 | 231.04 | 1,572 °C | — | 15.4 g/cm³ | 1.5 |
| Uranium | 92 | 238.03 | 1,135 °C | 4,131 °C | 19.1 g/cm³ | 1.38 |