Manganese (Mn)
Manganese (Mn) is a transition metal with atomic number 25 and a standard atomic weight of 54.938. At room temperature it is a solid that melts at 1,246 °C and boils at 2,061 °C.
Manganese key facts
Manganese at a glance
Identity
| Symbol | Mn |
|---|---|
| Atomic number (Z) | 25 |
| Atomic weight | 54.938 ± 0.001 (CIAAW 2024) |
| Category | Transition metal |
| Group | 7 |
| Period | 4 |
| Block | d-block |
| CAS number | 7439-96-5 |
Atomic properties
| Electron configuration | [Ar] 3d5 4s2 Full: 1s2 2s2 2p6 3s2 3p6 3d5 4s2 |
|---|---|
| Electrons per shell | 2, 8, 13, 2 |
| Oxidation states | +2, +4, +7 Less common: -3, -1, 0, +1, +3, +5, +6 |
| Electronegativity (Pauling) | 1.55 |
| First ionisation energy | 7.434 eV (717.3 kJ/mol) 2nd: 15.64 eV · 3rd: 33.668 eV |
| Atomic radius (empirical) | 140 pm |
| Covalent radius | 119 pm |
| Van der Waals radius | 205 pm |
Physical properties
| State at 25 °C | Solid |
|---|---|
| Melting point | 1,246 °C · 2,274.8 °F · 1,519.15 K |
| Boiling point | 2,061 °C · 3,741.8 °F · 2,334.15 K |
| Density | 7.3 g/cm³ |
| Specific heat capacity | 0.479 J/(g·K) |
| Crystal structure | Cubic |
Isotopes & abundance
| Natural occurrence | Primordial |
|---|---|
| Radioactive | No |
| Natural isotopes (abundance) | 55Mn 100% |
| Stable isotopes | 4 |
| Known isotopes | 31 |
| Abundance in Earth's crust | 950 mg/kg |
| Abundance in seawater | 0.0002 mg/L |
Atomic weights: CIAAW Abridged Standard Atomic Weights 2024. Other properties: standard reference compilations, checked October 2026; predicted values are marked.
Manganese electron configuration
Manganese has 25 electrons. Written in short form, its ground-state configuration is [Ar] 3d5 4s2 — the electrons of the noble gas argon, plus 3d5 4s2.Written out in full: 1s2 2s2 2p6 3s2 3p6 3d5 4s2.
Discovery and name
1774 — Johan Gottlieb Gahn (identified by Carl Wilhelm Scheele) · Sweden.
Latin magnes, magnet (via 'magnesia nigra').
Known for
Essential to steelmaking — about 90% of manganese goes into steel. Also used in aluminium cans and the cathodes of alkaline and lithium-ion batteries.
Isotopes of manganese
Naturally occurring manganese is a mix of 1 isotope. Each has 25 protons; they differ in the number of neutrons:
| Isotope | Protons | Neutrons | Natural abundance | Stability |
|---|---|---|---|---|
| 55Mn | 25 | 30 | 100% | stable |
31 isotopes of manganese are known in our data set (half-lives as published in nuclear data tables).
Manganese compared with group 7
The other elements in group 7, from top to bottom of the table:
| Element | Z | Atomic weight | Melting point | Boiling point | Density | Electronegativity |
|---|---|---|---|---|---|---|
| Manganese | 25 | 54.938 | 1,246 °C | 2,061 °C | 7.3 g/cm³ | 1.55 |
| Technetium | 43 | [97] | 2,157 °C | 4,262 °C | 11 g/cm³ | 1.9 |
| Rhenium | 75 | 186.21 | 3,185 °C | 5,590 °C | 20.8 g/cm³ | 1.9 |
| Bohrium | 107 | [270] | — | — | 37.1 g/cm³ (pred.) | — |